HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
trans-beta-METHYLSTYRENE → Trans-phenylpropylene oxide
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | trans-beta-METHYLSTYRENE | HCID 252325 | — |
| Edukt | Perfluorobutyrate | HCID 4342798 | — |
| Produkt | Benzaldehyde | HCID 240 | 30% |
| Produkt | Trans-phenylpropylene oxide | HCID 123339 | 70% |
Reaktionsschritte
The metal-catalyzed epoxidation of trans-β-methylstyrene was performed as described in Example 2 with the substitution of [Ru3O(pfb)6 (Et2O)3 ](pfb) (where pfb= perfluorobutyrate) (0.0449 g, 2.3×10-5 moles) as the catalyst. After 6 hours of reaction, the complete oxidation of the substrate produced benzaldehyde (30%) and 1-phenylpropylene oxide (70%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05274139 |
| Quelldatensatz | uspto-grants-1993_12 |
| ORD ID | ord-66613db6263748c8bb5ae234a7bbfdc5 |
| Quellennotiz | uspto-grants-1993_12 |