HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-(t-Butyldimethylsilyloxy)-1-hexyne → 5-[6-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]-1-hexynyl]-2H-1-benzopyran-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-(t-Butyldimethylsilyloxy)-1-hexyne | HCID 11009448 | — |
| Reactant | trifluoromethanesulfonic acid 2-oxo-2H-1-benzopyran-5-yl ester | HCID 54079840 | — |
| Product | 5-[6-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]-1-hexynyl]-2H-1-benzopyran-2-one | HCID 19921906 | 87% |
Reaction Steps
Using the procedure of example 120, trifluoromethanesulfonic acid 2-oxo-2H-1-benzopyran-5-yl ester from example 119 was converted to the title compound by reaction with (1,1-dimethylethyl)(5-hexynyloxy)dimethylsilane. The product was a solid, obtained in 87% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05273999 |
| Source dataset | uspto-grants-1993_12 |
| ORD ID | ord-6261b3fa888a4b2187de315653995fa0 |
| Source note | uspto-grants-1993_12 |