Ethanol → HCID 21443727, compound

HRID 328058Notes

Reaction equation

[CH2:1]([CH:6]1[CH:10]([C:11]#N)[CH2:9][CH2:8][C:7]1=[O:13])[CH2:2][CH:3]([CH3:5])[CH3:4].[OH2:14].[CH2:15]([OH:17])[CH3:16]>>[CH2:1]([CH:6]1[C:7](=[O:13])[CH2:8][CH2:9][CH:10]1[C:11]([O:17][CH2:15][CH3:16])=[O:14])[CH2:2][CH:3]([CH3:5])[CH3:4]

Participants

Reactant 3

HCID 702Ethanol

HCID 962Water

HCID 21443735HCID 21443735, compound

Product 1

HCID 21443727HCID 21443727, compoundYield 58%

Procedure

By repeating the procedure described in Example 16 but starting from 10 g 2-iso-pentyl-3-cyanocyclopentanone and 1 ml of water in 100 ml of absolute ethanol, there is obtained 7.3 g (58%) of ethyl 2-iso-pentyl-3-oxocyclopentanecarboxylate boiling at 84° C/0.25 mm, nD20 1.4530.

Sources & evidence

ORD record: ord-51f232ea3095494eaaa05da3702678ee
Source dataset: uspto-grants-1977_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04016109

Reaction notes

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