Ethylene Oxide → HCID 86733659, compound

HRID 328314Notes

Reaction equation

HRID 328314 reaction equation
[C:1]1([C:13]([OH:15])=[O:14])([C:10]([OH:12])=[O:11])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]1[C:7]([OH:9])=[O:8].[CH2:16]1[O:18][CH2:17]1>C(C(C)=O)C(C)C>[OH:8][CH2:7][CH2:2][O:14][C:13]([C:1]1([C:10]([O:12][CH2:17][CH2:16][OH:18])=[O:11])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]1[C:7]([O:9][CH2:1][CH2:10][OH:11])=[O:8])=[O:15]

Participants

4

Reactant 2

HCID 6354Ethylene OxideHCID 21896239HCID 21896239, compound

Product 1

HCID 86733659HCID 86733659, compound

Reagents, catalysts & solvents 1

HCID 7909Methyl Isobutyl KetoneSolvent

Procedure

Cyclohexanetricarboxylic acid was allowe to react under pressure with ethylene oxide and 0.15% of the catalyst of Example II (based on the total wt. of system) in the presence of methyl isobutyl ketone at 150°-160° C for 2 hours. A viscous oil of good purity was obtained after charcoal treatment and evaporation of a methyl isobutyl ketone solution. The infrared spectra and elements analysis were consistent with the desired product.

Workup

  1. customat 150°-160° C
  2. customfor 2 hours
  3. customA viscous oil of good purity was obtained
  4. customafter charcoal treatment and evaporation of a methyl isobutyl ketone solution

Sources & evidence

ORD record
ord-9da119d3ba644391afee850e5b61b119
Source dataset
uspto-grants-1977_04
Patent number
US04017429

Reaction notes

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