Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate → HCID 53814061, compound

HRID 328776Notes

Reaction equation

HRID 328776 reaction equation
COC([C:5]([S:29]([CH3:32])(=[O:31])=[O:30])([CH2:16][CH2:17][CH2:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])=O.COC(C(S(C)(=O)=O)(CC=CC(OC(=O)C)CCCCC)CCCCCCC(OC)=O)=O>>[CH3:32][S:29]([CH:5]([CH2:16][CH:17]=[CH:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])(=[O:30])=[O:31]

Participants

3

Reactant 2

HCID 21317603Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoateHCID 54170845Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxy-10-heptadecenoate

Product 1

HCID 53814061HCID 53814061, compound

Procedure

This compound is prepared by the procedure of Example 3, Step D, except that the methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methyoxycarbonyl-8-methylsulfonyl-12-acetoxy-10-heptadecenoate.

Sources & evidence

ORD record
ord-5d42bb15f63c48a9b67001c8298907fc
Source dataset
uspto-grants-1977_04
Patent number
US04018802

Reaction notes

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