Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate → HCID 21317639, compound

HRID 328783Notes

Reaction equation

HRID 328783 reaction equation
COC(C(S(C)(=O)=O)(CCCC(OC(=O)C)CCCCC)CCCCCCC(OC)=O)=O.COC([C:37]([S:63]([CH3:66])(=[O:65])=[O:64])([CH2:48][C:49]#[C:50][CH:51]([O:59][C:60](=[O:62])[CH3:61])[C:52]([CH3:58])([CH3:57])[CH2:53][CH2:54][CH2:55][CH3:56])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][C:44]([O:46][CH3:47])=[O:45])=O>>[CH3:66][S:63]([CH:37]([CH2:48][C:49]#[C:50][CH:51]([O:59][C:60](=[O:62])[CH3:61])[C:52]([CH3:57])([CH3:58])[CH2:53][CH2:54][CH2:55][CH3:56])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][C:44]([O:46][CH3:47])=[O:45])(=[O:64])=[O:65]

Participants

3

Reactant 2

HCID 21317603Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoateHCID 21317609HCID 21317609, compound

Product 1

HCID 21317639HCID 21317639, compound

Procedure

The synthesis of this compound is carried out by the procedure of Example 3, Step D, except that methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxy-13,13-dimethyl-10-heptadecynoate.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-44f6a73e5d9c4f2080aee44d216c9293
Source dataset
uspto-grants-1977_04
Patent number
US04018802

Reaction notes

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