HCID 21317585, compound → 8-Methylsulfonyl-11-(1-hydroxycyclohexyl)-10-undecynoic acid

HRID 328787Notes

Reaction equation

HRID 328787 reaction equation
[CH3:1][S:2]([CH:5]([CH2:16][CH2:17][CH2:18][CH:19]([O:25]C(=O)C)[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14]C)=[O:13])(=[O:4])=[O:3].CS(C(CC#CC1(OC(=O)C)CCCCC1)CCCCCCC(OC)=O)(=O)=O>>[CH3:1][S:2]([CH:5]([CH2:16][C:17]#[C:18][C:19]1([OH:25])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]1)[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])(=[O:3])=[O:4]

Participants

3

Reactant 2

HCID 21317585HCID 21317585, compoundHCID 21317665HCID 21317665, compound

Product 1

HCID 213175308-Methylsulfonyl-11-(1-hydroxycyclohexyl)-10-undecynoic acid

Procedure

The synthesis of this compound is carried out by the procedure of Example 3, Step E, except that methyl 8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methylsulfonyl-11-(1-acetoxycyclohexyl)-10-undecynoate.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-90330fc0088c427a931159557974c04d
Source dataset
uspto-grants-1977_04
Patent number
US04018802

Reaction notes

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