HCID 21440115, compound → HCID 21440165, compound

HRID 328947Notes

Reaction equation

HRID 328947 reaction equation
[C:1](C1C([N+]([O-])=O)=CC(C(O)=O)=CC=1O)(=O)[C:2]1C=CC=CC=1.[OH:22][C:23]1[CH:24]=[C:25]([CH:29]=[C:30]([N+:41]([O-:43])=[O:42])[C:31]=1[C:32](=[O:40])[C:33]1[CH:38]=[CH:37][C:36]([CH3:39])=[CH:35][CH:34]=1)[C:26]([OH:28])=[O:27]>>[OH:22][C:23]1[CH:24]=[C:25]([CH:29]=[C:30]([N+:41]([O-:43])=[O:42])[C:31]=1[C:32](=[O:40])[C:33]1[CH:34]=[CH:35][C:36]([CH3:39])=[CH:37][CH:38]=1)[C:26]([O:28][CH2:1][CH3:2])=[O:27]

Participants

3

Reactant 2

HCID 21440115HCID 21440115, compoundHCID 21440157HCID 21440157, compound

Product 1

HCID 21440165HCID 21440165, compound

Procedure

By replacing in Example 6, step A, 4-benzoyl-3hydroxy-5-nitrobenzoic acid with 3-hydroxy-4-(4'-methylbenzoyl)-5-nitrobenzoic acid and following the procedure described, ethyl 3-hydroxy-4-(4'-methylbenzoyl)-5-nitrobenzoate is obtained with a melting point of 145°-147° C.

Sources & evidence

ORD record
ord-05d4707d53b049de80d739b252d78db7
Source dataset
uspto-grants-1977_04
Patent number
US04018794

Reaction notes

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