HCID 21440130, compound → HCID 21440147, compound

HRID 328954Notes

Reaction equation

C(C1C([N+]([O-])=O)=CC(C(O)=O)=CC=1OCCCC)(=O)C1C=CC=CC=1.[CH2:26]([O:30][C:31]1[CH:32]=[C:33]([CH:37]=[C:38]([N+:49]([O-])=O)[C:39]=1[C:40](=[O:48])[C:41]1[CH:46]=[CH:45][C:44]([Cl:47])=[CH:43][CH:42]=1)[C:34]([OH:36])=[O:35])[CH2:27][CH2:28][CH3:29]>>[NH2:49][C:38]1[C:39]([C:40](=[O:48])[C:41]2[CH:42]=[CH:43][C:44]([Cl:47])=[CH:45][CH:46]=2)=[C:31]([O:30][CH2:26][CH2:27][CH2:28][CH3:29])[CH:32]=[C:33]([CH:37]=1)[C:34]([OH:36])=[O:35]

Participants

Reactant 2

HCID 21440130HCID 21440130, compound

HCID 21440143HCID 21440143, compound

Product 1

HCID 21440147HCID 21440147, compound

Procedure

By replacing in Example 1, step C, 4benzoyl-3-n-butoxy-5-nitrobenzoic acid with 3-n-butoxy-4-(4'-chlorobenzoyl)-5-nitrobenzoic acid and following the procedure described, 5-amino-3-n-butoxy-4-(4'-chlorobenzoyl)benzoic acid is obtained with a melting point of 286°-287.5° C.

Sources & evidence

ORD record: ord-1aa5f86a33f34d3a90b7e5b14ecd05d9
Source dataset: uspto-grants-1977_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04018794

Reaction notes

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