HCID 21440130, compound → HCID 21440119, compound

HRID 328955Notes

Reaction equation

HRID 328955 reaction equation
C(C1C([N+]([O-])=O)=CC(C(O)=O)=CC=1OCCCC)(=O)C1C=CC=CC=1.[CH2:26]([O:33][C:34]1[CH:35]=[C:36]([CH:40]=[C:41]([N+:52]([O-])=O)[C:42]=1[C:43](=[O:51])[C:44]1[CH:49]=[CH:48][C:47]([Cl:50])=[CH:46][CH:45]=1)[C:37]([OH:39])=[O:38])[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1>>[NH2:52][C:41]1[C:42]([C:43](=[O:51])[C:44]2[CH:45]=[CH:46][C:47]([Cl:50])=[CH:48][CH:49]=2)=[C:34]([O:33][CH2:26][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[CH:35]=[C:36]([CH:40]=1)[C:37]([OH:39])=[O:38]

Participants

3

Reactant 2

HCID 21440130HCID 21440130, compoundHCID 21440230HCID 21440230, compound

Product 1

HCID 21440119HCID 21440119, compound

Procedure

By replacing in Example 1, step C, 4-benzoyl-3-n-butoxy-5-nitrobenzoic acid with 3-benzyloxy-4-(4'-chlorobenzoyl)-5-nitrobenzoic acid and following the procedure described, 5-amino-3-benzyloxy-4-(4'-chlorobenzoyl)benzoic acid is obtained with a melting point of 196°-197° C.

Sources & evidence

ORD record
ord-b414d85e7618493f985a392b5c6e5178
Source dataset
uspto-grants-1977_04
Patent number
US04018794

Reaction notes

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