Methanol → HCID 21440163, compound

HRID 328973Notes

Reaction equation

HRID 328973 reaction equation
CO.[CH2:3](C1C(S(=O)(=O)N)=CC(C(O)=O)=CC=1SCCCC)[C:4]1C=CC=CC=1.[CH2:28]([C:35]1[C:43]([S:44](=[O:47])(=[O:46])[NH2:45])=[CH:42][C:38]([C:39]([OH:41])=[O:40])=[CH:37][C:36]=1[S:48][CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1)[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>C(O)C>[CH2:28]([C:35]1[C:43]([S:44](=[O:47])(=[O:46])[NH2:45])=[CH:42][C:38]([C:39]([O:41][CH2:3][CH3:4])=[O:40])=[CH:37][C:36]=1[S:48][CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1)[C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1

Participants

5

Reactant 3

HCID 887MethanolHCID 21440140HCID 21440140, compoundHCID 54516912HCID 54516912, compound

Product 1

HCID 21440163HCID 21440163, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

By replacing in Example 124, methanol with ethanol and 4-benzyl-3-n-butylthio-5-sulfamylbenzoic acid with 4-benzyl-3-benzylthio-5-sulfamylbenzoic acid and following the procedure described, ethyl 4-benzyl-3-benzylthio-5-sulfamylbenzoate is obtained with a melting point of 108°-110° C.

Sources & evidence

ORD record
ord-bc356cd8219547129e1274e07aa4492a
Source dataset
uspto-grants-1977_04
Patent number
US04018794

Reaction notes

Loading…