HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 5-(2-Carboxy-4-methoxybenzylidene)rhodanine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | Rhodanine | HCID 1201546 | — |
| Reactant | 2-Formyl-5-methoxybenzoic acid | HCID 7176205 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5-(2-Carboxy-4-methoxybenzylidene)rhodanine | HCID 53722834 | — |
Reaction Steps
To a hot stirred solution of 0.90 g. (5.0 mM) of 5-methoxyphthalaldehydic acid and 0.67 g. (5.0 mM) of rhodanine in 4 ml. of acetic acid is added 1.35 g. (16.4 mM) of anhydrous sodium acetate. After refluxing 0.5 hour, the solid yellow mass is cooled, poured into water, and filtered to separate 5-(2-carboxy-4-methoxybenzylidene)rhodanine as a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04018891 |
| Source dataset | uspto-grants-1977_04 |
| ORD ID | ord-78b68e9300d342368e5c865e380744f2 |
| Source note | uspto-grants-1977_04 |