Sodium Azide → HCID 21438642, compound

HRID 329151Notes

Reaction equation

HRID 329151 reaction equation
[CH3:1][O:2][C:3](=[O:18])[C:4]1[CH:9]=[C:8]([NH2:10])[CH:7]=[CH:6][C:5]=1[NH:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.N([O-])=O.[Na+].[N-:23]=[N+:24]=[N-].[Na+]>>[CH3:1][O:2][C:3](=[O:18])[C:4]1[CH:9]=[C:8]([N:10]=[N+:23]=[N-:24])[CH:7]=[CH:6][C:5]=1[NH:11][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1

Participants

4

Reactant 3

HCID 33557Sodium AzideHCID 21438651HCID 21438651, compoundHCID 23668193Sodium Nitrite

Product 1

HCID 21438642HCID 21438642, compound

Procedure

The same procedures as in Example A were repeated except that 10 parts of 2-phenylamino-5-aminobenzoic methyl ester were used as the starting compound, and the aqueous solution of 10% sodium nitrite and the aqueous solution of 10% sodium azide were used in amount of 28 parts and 33.2 parts, respectively, 2-phenylamino-5-azidobenzoic methyl ester having a melting point of 64° to 65° C was obtained at an amount of 9.5 parts.

Sources & evidence

ORD record
ord-ffb5e7a73f80478e95aef705d3ef800b
Source dataset
uspto-grants-1977_04
Patent number
US04019907

Reaction notes

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