HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methylbenzyl alcohol → HCID 12261648, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methylbenzyl alcohol | HCID 11505 | — |
| Reactant | Ethyl isothiocyanatoformate | HCID 85320 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | HCID 12261648 | HCID 12261648 | 106.7% |
Reaction Steps
66.5 g of ethoxycarbonyl isothiocyanate were added dropwise to a solution of 61 g of p-methylbenzyl alcohol in 500 ml of tetrahydrofuran and 2 ml of triethylamine and the mixture was refluxed for 24 hours. The mixture was concentrated to dryness to obtain 135 g of raw p-methylbenzyl N-carbethoxy -thiocarbamate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04020076 |
| Source dataset | uspto-grants-1977_04 |
| ORD ID | ord-f6c86d5d3dac45b18c693fd28e8b5960 |
| Source note | uspto-grants-1977_04 |