HCID 22759255, compound → HCID 22759283, compound

HRID 329288Notes

Reaction equation

HRID 329288 reaction equation
C(OC([C:6]([C:35](=[O:38])[CH2:36][CH3:37])([CH2:18][CH2:19][CH2:20][CH:21]([O:31]C(=O)C)[CH2:22][O:23][C:24]1[CH:29]=[CH:28][C:27]([F:30])=[CH:26][CH:25]=1)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([O:15]CC)=[O:14])=O)C.C(C(C(OCC)=O)(CCCC(OC(=O)C)COC1C=CC(F)=CC=1)CC#CCCCC(OC)=O)(=O)C>>[C:35]([CH:6]([CH2:18][CH2:19][CH2:20][CH:21]([OH:31])[CH2:22][O:23][C:24]1[CH:29]=[CH:28][C:27]([F:30])=[CH:26][CH:25]=1)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14])(=[O:38])[CH2:36][CH3:37]

Participants

3

Reactant 2

HCID 22759255HCID 22759255, compoundHCID 22759338HCID 22759338, compound

Product 1

HCID 22759283HCID 22759283, compound

Procedure

The synthesis of this compound is carried out by the procedure of Example 4, Step D except that an equivalent quantity of ethyl 8-ethoxycarbonyl-8-propionyl-12-acetoxy-13-(4-fluorophenoxy)tridecanoate is substituted for the methyl 8-acetyl-8-ethoxycarbonyl-12-acetoxy-13-(4-fluorophenoxy)-5-tridecynoate of Example 4, Step D.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-622c7c2c21e9458b9a12d3b420f0c949
Source dataset
uspto-grants-1977_04
Patent number
US04020177

Reaction notes

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