HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethylethanolamine → beta-N-N-diethylaminoethyl-2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethylethanolamine | HCID 7497 | — |
| Reactant | N-Ethyl-N-methylethanolamine | HCID 17916 | — |
| Reactant | HCID 12398827 | HCID 12398827 | — |
| Product | beta-N-N-diethylaminoethyl-2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionate | HCID 12398842 | — |
Reaction Steps
In similar manner substituting diethylethanolamine and N-ethyl-N-methylethanolamine for the dimethylethanolamine, there is obtained β-N-N-diethylaminoethyl-2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)propionate as an oil (hydrochloride salt: m.p. 117°-123° C; see Example XIV) and β-N-ethyl-N-methylaminoethyl 2-(5-oxo-5H-dibenzo[a,d]cyclohepten-2-yl)-propionate [an oil; n.m.r. spectrum in deuterochloroform relative to tetramethylsilane: 0.94 (triplet, CH2CH3); 1.53 (doublet, CHCH3); 2.08 (singlet, N--CH3); 4.17 (triplet, OCH2) and 7.03 ppm (singlet, 10H,11H); mass spectrum: 363 (M+), 305, 233, 205].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04020094 |
| Source dataset | uspto-grants-1977_04 |
| ORD ID | ord-539ff5670e564f4286e8b1c3c4675632 |
| Source note | uspto-grants-1977_04 |