1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine → [[2-[(Dimethylamino)methyl]phenyl]diphenylphosphoranylidene]carbamic acid, methyl ester

HRID 329655Notes

Reaction equation

HRID 329655 reaction equation
[C:1]1([P:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=2[CH2:14][N:15]([CH3:17])[CH3:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:24]([N:28]=[N+]=[N-])(=[O:27])[O:25][CH3:26]>CCOCC>[CH3:16][N:15]([CH2:14][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=1[P:7](=[N:28][C:24](=[O:27])[O:25][CH3:26])([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)[CH3:17]

Participants

4

Reactant 2

HCID 113706101-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamineHCID 12542276Azido(methoxy)methanone

Product 1

HCID 14771585[[2-[(Dimethylamino)methyl]phenyl]diphenylphosphoranylidene]carbamic acid, methyl ester

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

A 2.0 g portion of 2-(diphenylphosphino)-N,N-dimethylbenzenemethanamine was reacted with 4.0 ml of 1M methyl carbonazidate in ether as described in Example 1, giving 1.32 g of the desired product, mp 95°-97° C.

Sources & evidence

ORD record
ord-a7dcc481a2e1406a8e609828a94d9a47
Source dataset
uspto-grants-1990_01
Patent number
US04892885

Reaction notes

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