3-Tetradecylphenol → HCID 14819672, compound

HRID 329988Notes

Reaction equation

HRID 329988 reaction equation
[CH2:1]([C:15]1[CH:16]=[C:17]([OH:21])[CH:18]=[CH:19][CH:20]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]>N1C=CC=CC=1.C(Cl)(Cl)Cl>[C:17]([O:21][C:17]1[CH:18]=[CH:19][CH:20]=[C:15]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH:16]=1)(=[O:21])[CH2:16][CH2:15][CH2:1][CH2:2][CH3:3]

Participants

4

Reactant 1

HCID 144404953-Tetradecylphenol

Product 1

HCID 14819672HCID 14819672, compoundYield 195.2%

Reagents, catalysts & solvents 2

HCID 1049PyridineSolventHCID 6212ChloroformSolvent

Procedure

To a solution of 10.73 g of 3-tetradecylphenol in 30 ml of pyridine was added 8.02 g of hexanoic anyhydride. The mixture was stirred 24 hours, then diluted with chloroform, washed with water, then saturated aqueous sodium bicarbonate, dried and the solvent evaporated, giving 14.01 g of the desired compound.

Workup

  1. washwashed with water
  2. dry with materialsaturated aqueous sodium bicarbonate, dried
  3. customthe solvent evaporated

Sources & evidence

ORD record
ord-44576dffb72943b89f0be9147cd72cb1
Source dataset
uspto-grants-1990_01
Patent number
US04894367

Reaction notes

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