HuagongsheHuagongshe Chemistry Print Report · For research reference only
Maleic Anhydride → Adipate maleate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Maleic Anhydride | HCID 7923 | — |
| Reactant | Dimethyladipate | HCID 12329 | — |
| Reactant | Dibutyltin oxide | HCID 61221 | — |
| Reactant | Carbomethoxy-(2-hydroxyethyl)norbornene | HCID 70358522 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Adipate maleate | HCID 86743702 | — |
Reaction Steps
A resin cook apparatus is charged with carbomethoxy-(2-hydroxyethyl)norbornene (50 grams, 0.26 mole), dimethyl adipate (13.3 grams, 0.076 mole), maleic anhydride (17.5 grams, 0.18 mole), NPG (29.2 grams, 0.28 mole), and dibutyltin oxide (0.22 grams). The mixture is heated at 180° to 190° C. for 7 hours. A conversion of 72 percent is obtained based on the methanol taken overhead.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04895926 |
| Source dataset | uspto-grants-1990_01 |
| ORD ID | ord-0c749c92dfbe4e88a4aa3622e983ea0f |
| Source note | uspto-grants-1990_01 |