HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → 3-bromoindenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 5-Methoxyindan-1-one | HCID 78787 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 3-bromoindenone | HCID 11356251 | — |
Reaction Steps
5-methoxyindanone of formula 20 is dissolved in CCl4, N-bromosuccinimide (2 to 2.2 eq) and 2,2′-azobisisobutyronitrile (0.2 to 0.3 eq) are added thereto. The resulting mixture is further irradiated by a tungsten lamp (375W) for 3 to 5 h with stirring, to obtain the 3-bromoindenone of formula 21.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08877747B2 |
| Source dataset | uspto-grants-2014_11 |
| ORD ID | ord-f1ad0a4bfd5046a8a03c0a93ced7a273 |
| Source note | uspto-grants-2014_11 |