HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → 12,12,13,13,14,14,15,15,15-Nonafluoropentadecan-1-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | 10-Undecen-1-ol | HCID 8185 | — |
| Reactant | Perfluorobutyl iodide | HCID 67917 | — |
| Catalyst | Zinc | HCID 23994 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 12,12,13,13,14,14,15,15,15-Nonafluoropentadecan-1-ol | HCID 22630511 | — |
Reaction Steps
C4F9(CH2)11OAcr was prepared essentially as described above starting with the AIBN catalyzed addition of C4F9I to CH2═CH(CH2)9OH. The resulting iodohydrin was reduced with zinc in ethyl alcohol to give the desired C4F9(CH2)11OH and olefinic products in about an 80:20 ratio as follows.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08889230B2 |
| Source dataset | uspto-grants-2014_11 |
| ORD ID | ord-6a98f5f53abe48b59d60b178906d2901 |
| Source note | uspto-grants-2014_11 |