2-Hydroxyethyl acrylate → 2-(((3-(Methylsulfanyl)phenyl)carbamoyl)oxy)ethyl prop-2-enoate

Participants

Role	Name	HCID	Charge
Reactant	2-Hydroxyethyl acrylate	HCID 13165	—
Reactant	2,6-Di-tert-butyl-4-methylphenol	HCID 31404	—
Reactant	N,N',N''-Tris(3-dimethylaminopropyl)hexahydro-S-triazine	HCID 85160	—
Reactant	Isocyanate	HCID 105034	—
Reactant	3-(Methylthio)phenyl isocyanate	HCID 141418	—
Product	2-(((3-(Methylsulfanyl)phenyl)carbamoyl)oxy)ethyl prop-2-enoate	HCID 59273262	—

Reaction Conditions

Temperature	60 °C

Reaction Steps

0.02 g of 2,6-di-tert-butyl-4-methylphenol, 0.01 g of Desmorapid® Z, 11.7 g of 3-(methylthio)phenyl isocyanate were initially introduced and initially introduced into a 100 ml round-bottomed flask and heated to 60° C. Thereafter, 8.2 g of 2-hydroxyethyl acrylate were added dropwise and the mixture was further kept at 60° C. until the isocyanate content had fallen below 0.1%. Cooling was then effected. The product was obtained as a light yellow liquid. nD20:1.626.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08889321B2
Source dataset	uspto-grants-2014_11
ORD ID	ord-07b85c56bd1d447aa6d3d4b972c1e8b6
Source note	uspto-grants-2014_11