HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous chloride dihydrate → HCID 67312218, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | Ethyl acetate hexane | HCID 21226206 | — |
| Reactant | HCID 67311687 | HCID 67311687 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 67312218 | HCID 67312218 | 73.1% |
Reaction Steps
Prepared as described in the Nitro Reduction section using 4-nitro-3-trifluoromethyl-N-[4-(6-methoxybenzothiazol-2-yl)-phenyl]-benzamide (0.35 g, 0.74 mmol) and tin (II) chloride dihydrate (1.33 g, 5.91 mmol) in EtOH (7 ml) to give the title compound (0.24 g, 73%) as a pale yellow solid after work-up and flash chromatography (3:2 Hexane/EtOAc).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08895313B2 |
| Source dataset | uspto-grants-2014_11 |
| ORD ID | ord-c19de5d158c745dea8791b7acf088282 |
| Source note | uspto-grants-2014_11 |