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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 339585Generated: October 29, 2026

Benzaldehyde → HCID 58342013, compound

https://huagongshe.com/reaction/339585

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzaldehydeHCID 240—
ReactantHCID 13599214HCID 13599214—
ReactantEthyl acetate hexaneHCID 21226206—
ReactantPotassium tert-butoxideHCID 23665647—
SolventTetrahydrofuranHCID 8028—
ProductHCID 58342013HCID 5834201361.1%

Reaction Steps

Prepared as described in the Alkene Formation section using diethyl 4-(6-methylbenzothiazol-2-yl)benzylphosphonate (0.30 g, 0.80 mmol) in dry THF (15 ml), potassium t-butoxide (0.10 g, 0.88 mmol) and benzaldehyde (0.085 g, 0.80 mmol) in dry THF (5 ml) to give the title compound (0.16 g, 60%) as a pale yellow solid after work-up and flash chromatography (2:1 Hexane/EtOAc).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08895313B2
Source datasetuspto-grants-2014_11
ORD IDord-eb7aa5ae510848e9acab0cf6f4f4983b
Source noteuspto-grants-2014_11