HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous chloride dihydrate → HCID 67237158, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | Dichloromethane ethylacetate | HCID 21226138 | — |
| Reactant | HCID 67236914 | HCID 67236914 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 67237158 | HCID 67237158 | 39.2% |
Reaction Steps
Prepared as described in the Nitro Reduction section using 2-{4-[2-(2-nitrophenyl)-vinyl]-phenyl}-6-methylbenzothiazole (0.10 g, 0.268 mmol) and tin (II) chloride dihydrate (0.48 g, 2.15 mmol) in EtOH (3 ml) to give the title compound (0.036 g, 39%) as a yellow solid after work-up and flash chromatography (20:1 DCM/EtOAc).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08895313B2 |
| Source dataset | uspto-grants-2014_11 |
| ORD ID | ord-ceeb70fc97364d90b4f74e00e4f3e93d |
| Source note | uspto-grants-2014_11 |