HCID 54579177, compound → HCID 57268838, compound

HRID 340864Notes

Reaction equation

HRID 340864 reaction equation
C([O:4][CH2:5][CH2:6][C:7]([O:10][C:11]([CH3:19])([CH3:18])[CH2:12][CH2:13][O:14]C(=O)C)([CH3:9])[CH3:8])(=O)C>N>[O:10]([C:11]([CH3:19])([CH3:18])[CH2:12][CH2:13][OH:14])[C:7]([CH3:8])([CH3:9])[CH2:6][CH2:5][OH:4]

Participants

3

Reactant 1

HCID 54579177HCID 54579177, compound

Product 1

HCID 57268838HCID 57268838, compound

Reagents, catalysts & solvents 1

HCID 222AmmoniaSolvent

Procedure

To a flask containing 3,3′-oxybis(3-methylbutan-1-yl) diacetate (0.274 g, 1 mmol), was added 10 mL of 2.0N methanolic ammonia and the reaction was stirred overnight at room temperature. Solvent was then removed under reduced pressure. Compound was then dissolved in 20 mL diethyl ether and precipitate was filtered out. Filtrate was then reduced under vacuum to yield a colorless liquid. (0.187 g yield) 1H NMR (400 MHz, CDCl3): δ 1.61 (s, 12H), 2.04 (t, J=6.6, 4H), 3.88 (t, J=6.6, 4H).

Workup

  1. customSolvent was then removed under reduced pressure
  2. dissolutionCompound was then dissolved in 20 mL diethyl ether
  3. filtrationprecipitate was filtered out
  4. customto yield a colorless liquid
  5. custom(0.187 g yield) 1H NMR (400 MHz, CDCl3): δ 1.61 (s, 12H), 2.04 (t, J=6.6, 4H), 3.88 (t, J=6.6, 4H)

Sources & evidence

ORD record
ord-01a61cff903447798ee743152899bb0f
Source dataset
uspto-grants-2014_11
Patent number
US08895691B2

Reaction notes

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