HRID340872

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID222

Ammonia gas

H3N

结构：CC(=O)Oc1cc(C(=O)Cl)cc(C(=O)Cl)c1.CC(C)(CCC(C)(C)OC(=O)CO)OC(=O)CO.O=C(Cl)c1cccc(C(=O)Cl)c1

HCID131732089

未命名化合物

PRODUCTS

生成物

结构：CC(C)(CCC(C)(C)OC(=O)CO)OC(=O)CO.O=C(Cl)c1cc(O)cc(C(=O)Cl)c1.O=C(Cl)c1cccc(C(=O)Cl)c1

HCID131732090

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

To a solution of methanolic ammonia (20 mL, 1 N), polymer (118) dissolved in 5 mL tetrahydrofuran was added and the solution was stirred for two hours. The polymer was then precipitated in 100 mL of cold 1 N hydrochloric acid and collected by filtration. The polymer was then dried under high vacuum and was found to have a molecular weight of ˜7,000 g/mol by GPC.

WORKUP

后处理

additionwas added
customThe polymer was then precipitated in 100 mL of cold 1 N hydrochloric acid
filtrationcollected by filtration
customThe polymer was then dried under high vacuum

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-749641c63b9a48d08b5f6811c9161a92
来源数据集: uspto-grants-2014_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08895691B2
来源说明: uspto-grants-2014_11

反应 SMILES

N.[OH:2][CH2:3][C:4]([O:6][C:7]([CH3:19])([CH2:9][CH2:10][C:11]([O:14][C:15](=[O:18])[CH2:16][OH:17])([CH3:13])[CH3:12])[CH3:8])=[O:5].[C:20]([Cl:31])(=[O:30])[C:21]1[CH:29]=[CH:28][CH:27]=[C:23]([C:24]([Cl:26])=[O:25])[CH:22]=1.C([O:35][C:36]1[CH:37]=[C:38]([C:45]([Cl:47])=[O:46])[CH:39]=[C:40]([CH:44]=1)[C:41]([Cl:43])=[O:42])(=O)C>O1CCCC1>[OH:2][CH2:3][C:4]([O:6][C:7]([CH3:19])([CH2:9][CH2:10][C:11]([O:14][C:15](=[O:18])[CH2:16][OH:17])([CH3:12])[CH3:13])[CH3:8])=[O:5].[C:24]([Cl:26])(=[O:25])[C:23]1[CH:27]=[CH:28][CH:29]=[C:21]([C:20]([Cl:31])=[O:30])[CH:22]=1.[OH:35][C:36]1[CH:44]=[C:40]([C:41]([Cl:43])=[O:42])[CH:39]=[C:38]([CH:37]=1)[C:45]([Cl:47])=[O:46]