HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Dithionite → 3-Amino-1,2,4-benzotriazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Dithionite | HCID 24489 | — |
| Reactant | 3-Amino-1,2,4-benzotriazine-1-oxide | HCID 79470 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 3-Amino-1,2,4-benzotriazine | HCID 88336 | — |
Reaction Steps
A mixture of 8.1 g (49 mmol) 1,2,4-benzotriazine-3-amine 1-oxide, 8.1 g sodium dithionite and 800 ml 70 percent ethanol is heated under reflux for 1 h. One filters hot, evaporates the filtrate, washes the residue with water and dries. There remain 7.0 g 1,2,4-benzotriazine-3-amine (98% of theory) of the m.p. 208°-210° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05856325 |
| Source dataset | uspto-grants-1999_01 |
| ORD ID | ord-c226919073fc4fcab20174f586860c05 |
| Source note | uspto-grants-1999_01 |