HCID 22168605, compound → HCID 22168686, compound

HRID 341883Notes

Reaction equation

HRID 341883 reaction equation
[CH3:1][N:2]([CH3:17])[C:3]([C:5]1[C:13]([N+:14]([O-:16])=[O:15])=[CH:12][CH:11]=[CH:10][C:6]=1[C:7]([OH:9])=[O:8])=[O:4].[CH2:18](OC1C=C(C=C(N)C=1)C(OCC=C)=O)[CH:19]=[CH2:20]>>[CH3:1][N:2]([CH3:17])[C:3]([C:5]1[C:13]([N+:14]([O-:16])=[O:15])=[CH:12][CH:11]=[CH:10][C:6]=1[C:7]([O:9][CH2:20][CH:19]=[CH2:18])=[O:8])=[O:4]

Participants

3

Reactant 2

HCID 22168605HCID 22168605, compoundHCID 221686192-Dimethylaminocarbonyl-3-nitrobenzoic acid

Product 1

HCID 22168686HCID 22168686, compound

Procedure

2-Dimethylaminocarbonyl-3-nitrobenzoic acid (1 g) was to the allyl ester by a similar method to that described in example 1 for the formation of allyl 3-allyloxy-5-aminobenzoate giving allyl 2-dimethylaminocarbonyl-3-nitrobenzoate (0.88 g). Nmr (DMSO-d6): δ 2.45 (s, 3H); 2.97 (s, 3H); 4.79 (dd, 2H); 5.28-5.47 (m, 2H); 5.9-6.1 (m, 1H); 7.81 (t, 1H); 8.28-8.4 (dq, 2H).

Sources & evidence

ORD record
ord-1e30817919c244a0b17970d5b103e212
Source dataset
uspto-grants-1999_01
Patent number
US05856321

Reaction notes

Loading…