HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → cis-Pinanediol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | (+-)-alpha-Pinene | HCID 6654 | — |
| Reactant | Methyl morpholine oxide | HCID 82029 | — |
| Product | cis-Pinanediol | HCID 70359975 | — |
Reaction Steps
A process for producing 2-hydroxy-3-pinanone, comprising the steps of reacting α-pinene with catalytic potassium osmate in solution of pyridine, N-methylmorpholine-N-oxide and aqueous acetone to produce cis-pinanediol; and thereafter oxidizing said cis-pinanediol with DMSO activated by pyridine.SO3 and triethylamine in an appropriate solvent to produce 2-hydroxy-3-pinanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05856497 |
| Source dataset | uspto-grants-1999_01 |
| ORD ID | ord-24eadf45c8c849a6a1c06f8f116ccb3e |
| Source note | uspto-grants-1999_01 |