HRID34256

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1140

Toluene

C7H8

HCID8919

1-Bromododecane

C12H25Br

HCID14797

Potassium hydroxide

HKO

HCID135624294

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCCCOC1(OC(C)CCCCCC)C=CC(N=Nc2ccccc2)=CC1

HCID70406108

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

The above crude product of 4-(1-methyl-heptyloxy)-4'-hydroxy-azobenzene (16.5 g) was heated with lauryl bromide (16 g) in ethanol in the presence of KOH (3.6 g) under reflux for 10 hours, followed by passing a toluene solution of the product through an alumina chromatographic column and recrystallizing from heptane to obtain 4'-dodecyloxy-4'-(1-methyl-heptyloxy)-azobenzene

WORKUP

后处理

temperatureunder reflux for 10 hours
customrecrystallizing from heptane

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-28693ca372ef4f7ba550b18e0dc78d51
来源数据集: uspto-grants-1988_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04761246
来源说明: uspto-grants-1988_08

反应 SMILES

[CH3:1][CH:2]([O:9][C:10]1[CH:15]=[CH:14][C:13]([N:16]=[N:17][C:18]2[CH:23]=[CH:22][C:21](O)=[CH:20][CH:19]=2)=[CH:12][CH:11]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:25](Br)[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36].[OH-:38].[K+].C1(C)C=CC=CC=1>C(O)C>[CH2:25]([O:38][C:10]1([O:9][CH:2]([CH3:1])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH:15]=[CH:14][C:13]([N:16]=[N:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[CH:12][CH2:11]1)[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36]