化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Hydroxide → 4-(6-Hydroxyhexyloxy)-4'-methoxybiphenyl
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 6-Bromo-1-hexanol | HCID 77970 | — |
| 反応物 | 4-Hydroxy-4'-methoxybiphenyl | HCID 11030839 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 4-(6-Hydroxyhexyloxy)-4'-methoxybiphenyl | HCID 44630340 | 76% |
反応手順
Using 5 g (25 mmol) of 4-methoxy-4'-hydroxybiphenyl, 50 ml of ethanol, 4.52 g (25 mmol) of 6-bromo-1-hexanol and a NaOH aqueous solution (1.05 g (26.2 mmol) of NaOH/3 ml of water), synthetic treatment was carried out in the same manner as in Example 1. The obtained crystals were recrystallized from methanol to obtain 5.71 g (yield: 76%) of 4-methoxy-4'-(6-hydroxyhexyloxy)biphenyl (13) as colorless crystals.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05861534 |
| 出典データセット | uspto-grants-1999_01 |
| ORD ID | ord-21e7484b81a640d3b68e7e6cfeafe85e |
| 出典メモ | uspto-grants-1999_01 |