Fumaric Acid → Fumaric acid molybdenum

HRID 343733Notes

Reaction equation

HRID 343733 reaction equation
[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]/[C:4]([OH:6])=[O:5].C([O-])(=O)C.[Mo+4:13].C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C>CO>[Mo:13].[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]/[C:4]([OH:6])=[O:5]

Participants

4

Reactant 2

HCID 444972Fumaric AcidHCID 11473018Molybdenum acetate

Product 1

HCID 87139920Fumaric acid molybdenum

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

0.597 g (5.14 mmol) of fumaric acid and 1,000 g (2.34 mmol) of molybdenum acetate were dissolved in 900 ml of methanol. After this was stirred for three days at the room temperature, this was kept still for a few days. Thereafter, its precipitation product was suction-filtered, rinsed sufficiently with methanol and then vacuum-dried for 60° C./4 hours, whereby 0.970 g of target substance was obtained. This substance had the specific surface area of 469 m2 /g. And, a measurement according to the HK method using argon revealed that the substance had the pore diameter of 5.8 Å.

Workup

  1. waitthis was kept still for a few days
  2. customThereafter, its precipitation product
  3. filtrationwas suction-filtered
  4. washrinsed sufficiently with methanol
  5. customvacuum-dried for 60° C./4 hours, whereby 0.970 g of target substance
  6. customwas obtained

Sources & evidence

ORD record
ord-16e899be161344d6ac639b79393768ec
Source dataset
uspto-grants-1999_01
Patent number
US05862796

Reaction notes

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