HCID 86745127, compound → HCID 178444365, compound

HRID 344981Notes

Reaction equation

HRID 344981 reaction equation
[CH2:1]([CH:6]1[CH2:11][CH2:10][C:9]([C:12]2[CH:17]=[CH:16][C:15]([S:18]([F:23])([F:22])([F:21])([F:20])[F:19])=[CH:14][CH:13]=2)=[CH:8][CH2:7]1)[CH2:2][CH2:3][CH2:4][CH3:5]>[Pd].C1(C)C=CC=CC=1>[CH2:1]([C@H:6]1[CH2:7][CH2:8][C@H:9]([C:12]2[CH:13]=[CH:14][C:15]([S:18]([F:23])([F:19])([F:20])([F:21])[F:22])=[CH:16][CH:17]=2)[CH2:10][CH2:11]1)[CH2:2][CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 1

HCID 86745127HCID 86745127, compound

Product 1

HCID 178444365HCID 178444365, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 1140TolueneSolvent

Procedure

A mixture of 6.5 g of 4-(4-pentylcyclohex-1-enyl)-phenyl-sulfur pentafluoride, 0.5 g of palladium-on-active charcoal (1%) and 40 ml of toluene is hydrogenated at room temperature under normal pressure until saturation is reached. Removing the solvent by distillation and working up in the customary manner gives 4-(trans-4-pentylcyclohexyl)-phenyl-sulfur pentafluoride.

Workup

  1. customis hydrogenated at room temperature under normal pressure until saturation
  2. customRemoving the solvent
  3. distillationby distillation

Sources & evidence

ORD record
ord-541d1fb200604524910e3aeac9d51e9b
Source dataset
uspto-grants-1991_10
Patent number
US05055223

Reaction notes

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