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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 345352Generated: October 29, 2026

(Triphenylphosphoranylidene)acetaldehyde → HCID 56607884, compound

https://huagongshe.com/reaction/345352

Reaction equation

Participants

RoleNameHCIDCharge
Reactant(Triphenylphosphoranylidene)acetaldehydeHCID 75051—
ReactantHCID 14541450HCID 14541450—
SolventTolueneHCID 1140—
ProductHCID 56607884HCID 56607884—

Reaction Steps

A solution of 1 g of 1-(tert-butoxycarbonyl)-2-ethoxycarbonylpiperidine-4-carboxaldehyde and 2 g of formylmethylene-triphenylphosphoran in 16 ml of toluene is heated to 100° (bath) for 2 hours. The solution is cooled and purified by flash chromatography using ethyl acetate/hexane (25:75) to yield 1-(tert-butoxycarbonyl)-2-ethoxycarbonylpiperidine-4-acrylaldehyde.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05057506
Source datasetuspto-grants-1991_10
ORD IDord-6baffcad456e408eb64a0d3a461d7608
Source noteuspto-grants-1991_10