HRID345622

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID69297

N-Benzyl-N-hydroxy-1-phenylmethanamine

C14H15NO

HCID169132

Isophorone diisocyanate

C12H18N2O2

PRODUCTS

生成物

结构：CC1(C)CC(NC(=O)ON(Cc2ccccc2)Cc2ccccc2)CC(C)(CNC(=O)ON(Cc2ccccc2)Cc2ccccc2)C1

HCID15180716

Carbamic acid, N-[3-[[[[[bis(phenylmethyl)amino]oxy]carbonyl]amino]methyl]-3,5,5-trimethylcyclohexyl]-, bis(phenylmethyl)azanyl ester

C40H48N4O4

PROCEDURE

实验过程

The procedure of Example 1 is repeated using 10.66 g (50 mmol) of N,N-dibenzylhydroxylamine and 5.56 g (25 mmole) of 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate. The residue is recrystallized from a 1:1 heptane: toluene solvent mixture to give 11.0 g (68%) of a white soldi, m.p. 139°-146° C.

WORKUP

后处理

customThe residue is recrystallized from a 1:1 heptane
customtoluene solvent mixture to give 11.0 g (68%) of a white soldi, m.p. 139°-146° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-095f55741929481cb0eafb9e9807fb1f
来源数据集: uspto-grants-1991_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05057610
来源说明: uspto-grants-1991_10

反应 SMILES

[CH2:1]([N:8]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[OH:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N:17]([CH2:20][C:21]1([CH3:32])[CH2:26][C:25]([CH3:28])([CH3:27])[CH2:24][CH:23]([N:29]=[C:30]=[O:31])[CH2:22]1)=[C:18]=[O:19]>>[CH2:10]([N:8]([O:9][C:30]([NH:29][CH:23]1[CH2:24][C:25]([CH3:27])([CH3:28])[CH2:26][C:21]([CH2:20][NH:17][C:18]([O:9][N:8]([CH2:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH2:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:19])([CH3:32])[CH2:22]1)=[O:31])[CH2:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1