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Potassium Carbonate → 1,2-Dimethyl-3-oxa-2,7-diazabicyclo[3.3.0]octane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 7-Acetyl-1,2-dimethyl-3-oxa-2,7-diazabicyclo[3.3.0]octane | HCID 15070017 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1,2-Dimethyl-3-oxa-2,7-diazabicyclo[3.3.0]octane | HCID 15070018 | — |
反応手順
11.8 g (64 mmol) of 7-acetyl-1,2-dimethyl-3-oxa-2,7-diazabicyclo[3.3.0]octane are heated under reflux with 12 g of NaOH in 36 ml of water overnight. The mixture is saturated with K2CO3 and extracted several times with CHCl3, the extract is dried over K2CO3 and concentrated and the residue is distilled.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05059597 |
| 出典データセット | uspto-grants-1991_10 |
| ORD ID | ord-b9c6520b46094dc98b1ea6c72a4a8901 |
| 出典メモ | uspto-grants-1991_10 |