HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 19991617, compound → HCID 19991589, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 19991617 | HCID 19991617 | — |
| Reactant | Jones' reagent | HCID 131709961 | — |
| Product | HCID 19991589 | HCID 19991589 | — |
Reaction Steps
3-(10-Hydroxydecyl)-5-trimethylsilylfuran is oxidized by Jones reagent (chromic acid) to give 3-(10-carboxydecyl)-5-trimethylsilylfuran. A mixture of this compound and Rose Bengal in tetrahydrofuran is exposed to singlet oxygen at -78° to give 4-(10-carboxydecyl)-5-hydroxy-2(5H)-furanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05059611 |
| Source dataset | uspto-grants-1991_10 |
| ORD ID | ord-bfc8085ab612427ca308d685be21d54d |
| Source note | uspto-grants-1991_10 |