HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 2-Furyltrimethylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | 3-(2-Trimethylsilyl-4-furyl)propan-1-al | HCID 15037092 | — |
| Reactant | 2,2-Dioctylpropanedioate | HCID 22059025 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-Furyltrimethylsilane | HCID 137092 | — |
Reaction Steps
3-(2-Trimethylsilyl-4-furyl)propan-1-al is reacted with dioctylmalonate in tetrahydrofuran in the presence of acetic acid and piperidine to give 3-[4,4-di (carbooctanoxy)-3-butenyl]- 5-trimethylsilylfuran which is treated with cold aqueous potassium hydroxide to give 3-(4-carboxy-4-carbooctanoxy-3-butenyl)-5-trimethylsilylfuran.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05059611 |
| Source dataset | uspto-grants-1991_10 |
| ORD ID | ord-f22021f889e543469ccef2e7d86fe91e |
| Source note | uspto-grants-1991_10 |