HCID 19991618, compound → HCID 19991598, compound

Participants

Reaction Steps

Jones reagent (a 2.67M solution in sulfuric acid; 50 μl, 0.14 mmol) was added to a solution of 4-(3-hydroxy-4-hexadecynyl)-2-triethylsilylfuran (53.6 mg, 0.13 mmol) in acetone (5 ml) at 0°. After 25 minutes, the mixture was quenched with ethanol, diluted with water and was extracted with ethyl ether. Evaporation of the dried (magnesium sulfate) extracts gave an oil, which was purified by preparative silica plates to give the titled ketone.

Provenance & Evidence