31001-73-7 → HCID 178514295, compound

HRID 345913Notes

Reaction equation

HRID 345913 reaction equation
[OH:1][C:2]1[C:15]([O:16]S(C2C3C=CC(=[N+]=[N-])C(=O)C=3C=CC=2)(=O)=O)=[C:14]([O:33][S:34]([C:37]2[C:46]3[CH:45]=[CH:44][C:43](=[N+:47]=[N-:48])[C:42](=[O:49])[C:41]=3[CH:40]=[CH:39][CH:38]=2)(=[O:36])=[O:35])[CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5].[N+](=C1C=CC2C(S(OC3C=CC(C(C4C=CC(OS(C5C6C=CC(=[N+]=[N-])C(=O)C=6C=CC=5)(=O)=O)=CC=4)=O)=CC=3)(=O)=O)=CC=CC=2C1=O)=[N-].OC1C=C(OS(C2C3C=CC(=[N+]=[N-])C(=O)C=3C=CC=2)(=O)=O)C=CC=1C(C1C=CC=CC=1)=O.[N+](=C1C=CC2C(S(OC3C=C(OS(C4C5C=CC(=[N+]=[N-])C(=O)C=5C=CC=4)(=O)=O)C=CC=3C(C3C=CC=CC=3)=O)(=O)=O)=CC=CC=2C1=O)=[N-].BrC(CBr)COS(C1C2C=CC(=[N+]=[N-])C(=O)C=2C=CC=1)(=O)=O.[N+](=C1C=CC2C(S(OC3CCC(C(C4CCC(OS(C5C6C=CC(=[N+]=[N-])C(=O)C=6C=CC=5)(=O)=O)CC4)(C)C)CC3)(=O)=O)=CC=CC=2C1=O)=[N-]>>[OH:1][C:2]1[C:15]([OH:16])=[C:14]([O:33][S:34]([C:37]2[C:46]3[CH:45]=[CH:44][C:43](=[N+:47]=[N-:48])[C:42](=[O:49])[C:41]=3[CH:40]=[CH:39][CH:38]=2)(=[O:36])=[O:35])[CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]

Participants

7

Reactant 6

HCID 13616496831001-73-7HCID 1383957671-Naphthalenesulfonic acid, 6-diazo-5,6-dihydro-5-oxo-, 2,3-dibromopropyl esterHCID 178439334HCID 178439334, compoundHCID 178514294HCID 178514294, compoundHCID 178514296HCID 178514296, compoundHCID 178514298HCID 178514298, compound

Product 1

HCID 178514295HCID 178514295, compound

Procedure

2-hydroxy-3,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) benzophenone (1); 2,3,4-tris(6-diazo-5,6-dihydro-5-oxy-1-naphthalenesulfonyloxy) benzophenone (11); 4,4'-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) benzophenone (12); 2-hydroxy-4-(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) benzophenone (2); 2,4-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) benzophenone (15); or 2,3-dibromo-1-(6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonyloxy) propane (17); or 4,4'-bis(6-diazo-5,6-dihydro-5-oxo-1-naphthalene sulfonyloxy)isopropylidenebiscyclohexane (18).

Sources & evidence

ORD record
ord-7804957555b84ac8997cff70998280b3
Source dataset
uspto-grants-1991_10
Patent number
US05059513

Reaction notes

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