HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-(2-Bromoethyl)-3,5-dimethyl Adamantane → 1,3-Dimethyl-5-ethyladamantane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-(2-Bromoethyl)-3,5-dimethyl Adamantane | HCID 15068767 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 1,3-Dimethyl-5-ethyladamantane | HCID 519331 | 86% |
Reaction Steps
Dissolve 0.5 mol of 1-(2-bromoethyl)-3,5-dimethyl adamantane (II) in toluene, mix with 0.55 mol of sodium-bis(2-methoxy-ethoxy)dihydro aluminate, and heat to boiling for 3 hrs. After hydrolysis, separate the organic phase, dry with magnesium sulfate, and evaporate to dryness under vacuum. Purify the residue by vacuum distillation. (Yield: 86%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05061703 |
| Source dataset | uspto-grants-1991_10 |
| ORD ID | ord-5d051d4d1f9e4b0996b7cf3a190c421c |
| Source note | uspto-grants-1991_10 |