HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexene → HCID 21082854, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexene | HCID 8079 | — |
| Reactant | 1-Methylpiperazine | HCID 53167 | — |
| Reactant | 2-Chloro-3,5-dinitropyridine | HCID 75738 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 21082854 | HCID 21082854 | — |
Reaction Steps
2 g of 1-(3,5-dinitropyrid-2-yl)-4-methylpiperazine, obtained according to Protocol A from 2-chloro-3,5-dinitropyridine and 4-methylpiperazine, were reduced by hydrogen transfer in 50 ml of ethanol in the presence of palladium-on-charcoal and 5 ml of cyclohexene. 1.63 g of 2-(4-methylpiperazin-1-yl)pyridine-3,5-diamine were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07175670B2 |
| Source dataset | uspto-grants-2007_02 |
| ORD ID | ord-5b60f4ec84004133af22c6a0f06a40b4 |
| Source note | uspto-grants-2007_02 |