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Phosphorus oxychloride → HCID 14256186、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phosphorus oxychloride | HCID 24813 | — |
| 反応物 | 1-Bromo-2-propanol | HCID 29740 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | HCID 14256186 | HCID 14256186 | 42.2% |
反応手順
To a solution of 46 g of phosphorus oxychloride in 110 ml of carbon tetrachloride was added with stirring 21 g of 1-bromo-2-propanol. The mixture was stirred overnight, the solvent removed and the residue evaporated twice from toluene at 35° C., then evaporated to dryness giving a dark oil. This oil was distilled on a Kugelrohr at 75° C., 0.3 mm giving 16.3 g of the desired compound as a white oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04762942 |
| 出典データセット | uspto-grants-1988_08 |
| ORD ID | ord-e3ab952f95f3447d8425a816cc6768d0 |
| 出典メモ | uspto-grants-1988_08 |