HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodobenzene → 3-methyl-N,N-diphenylaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodobenzene | HCID 11575 | — |
| Reactant | N-(3-Methylphenyl)aniline | HCID 14569 | — |
| Catalyst | Copper | HCID 23978 | — |
| Product | 3-methyl-N,N-diphenylaniline | HCID 11086477 | 75% |
Reaction Steps
The same equipment and conditions as in example I were employed with the following charge: 20.4 grams (0.1 mole) iodobenzene, 27.5 grams (0.15 mole) 3-methyldiphenylamine, 15.0 grams copper powder and 30.0 milliliters of Soltrol® 170. The above-identified intended product was obtained as colorless crystals having a melting point of 69°-70° C. Yield 75%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04764625 |
| Source dataset | uspto-grants-1988_08 |
| ORD ID | ord-b130051439054dada6006afe8ea910ee |
| Source note | uspto-grants-1988_08 |