1-Octanol → octyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

HRID 35167Notes

Reaction equation

HRID 35167 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH2:18]([OH:26])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:26][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 9571-OctanolHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

Product 1

HCID 20041726octyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and 1-octanol there is obtained octyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a resinous product, 1H-NMR(CDCl3): 0.88 (t, CH3), 1.0-2.0 (12H), 4.15 (t, OCH2), 4.23 (s, 4H), 4.87 (broad s, NH), 7.3-7.7 (8H);

Sources & evidence

ORD record
ord-73ceb965679645928c9e00d691870bf7
Source dataset
uspto-grants-1988_08
Patent number
US04766115

Reaction notes

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