HRID354531

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11120

Ethanedioic acid, dimethyl ester

C4H6O4

结构：CC(O)CNCCNc1ccc(NCCNCC(C)O)c2c1C(=O)c1c(O)ccc(O)c1C2=O

HCID433060

1,4-dihydroxy-5,8-bis[2-(2-hydroxypropylamino)ethylamino]anthracene-9,10-dione

C24H32N4O6

PRODUCTS

生成物

结构：CC(O)CNCCNc1ccc(NCCN2CC(C)OC(=O)C2=O)c2c1C(=O)c1c(O)ccc(O)c1C2=O

HCID20507737

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID679

Dimethyl sulfoxide

C2H6OS

PROCEDURE

实验过程

A solution of 2.60 g of 1,4-dihydroxy-5,8-bis-[2-(2-hydroxypropylamino)ethylamino]anthraquinone (prepared in Example 3) and 0.650 g of dimethyl oxalate in 25.0 ml of dried dimethyl sulfoxide is processed as described in Example 2 to give the desired product as a blue-black solid.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-defe00d2a9484bd88cdf4bf3474bf634
来源数据集: uspto-grants-1983_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04375469
来源说明: uspto-grants-1983_03

反应 SMILES

[OH:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9]([NH:25][CH2:26][CH2:27][NH:28][CH2:29][CH:30]([OH:32])[CH3:31])[CH:10]=[CH:11][C:12]=3[NH:17][CH2:18][CH2:19][NH:20][CH2:21][CH:22]([OH:24])[CH3:23])[C:7](=[O:33])[C:6]=2[C:5]([OH:34])=[CH:4][CH:3]=1.[C:35](OC)(=[O:40])[C:36](OC)=[O:37]>CS(C)=O>[CH3:31][CH:30]1[O:32][C:36](=[O:37])[C:35](=[O:40])[N:28]([CH2:27][CH2:26][NH:25][C:9]2[C:8]3[C:7](=[O:33])[C:6]4[C:15](=[C:2]([OH:1])[CH:3]=[CH:4][C:5]=4[OH:34])[C:14](=[O:16])[C:13]=3[C:12]([NH:17][CH2:18][CH2:19][NH:20][CH2:21][CH:22]([OH:24])[CH3:23])=[CH:11][CH:10]=2)[CH2:29]1