Triethylamine → HCID 86738804, compound

Participants

Reaction Steps

Triethylamine (0.5 gram, 0.005 mole) was added to a solution of (3-amino-2,6-dimethylphenyl)methyl cis-3-(2-chloro-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylate (2.03 grams, 0.005 mole) in chloroform (20 ml) and cooled to 0°. Thiophosgene (0.58 gram, 0.005 mole) was added, and the reaction mixture was allowed to come to room temperature. The solvent was evaporated, and the residue was dissolved in diethyl ether. The solution was washed with water, dried over magnesium sulfate and filtered. The solvent was evaporated to give (3-isothiocyanato-2,6-dimethylphenyl)methyl cis-3-(2-chloro-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylate (1.71 grams, mp 60°).

Provenance & Evidence