2-Nitrotoluene → Hydrazine, 1,2-bis(2-methylphenyl)-

HRID 354617Notes

Reaction equation

HRID 354617 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH3:10])([O-])=O>CS(C)=O>[CH3:10][C:5]1[C:4]([NH:1][NH:1][C:4]2[C:5]([CH3:10])=[CH:6][CH:7]=[CH:8][CH:9]=2)=[CH:9][CH:8]=[CH:7][CH:6]=1

Participants

3

Reactant 1

HCID 69442-Nitrotoluene

Product 1

HCID 69234Hydrazine, 1,2-bis(2-methylphenyl)-Yield 93%

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

An identical reduction of o-nitrotoluene as described in example 7 was carried out, except 1.8 g of dimethyl sulfoxide was added to the reaction mixture. This reduction resulted in a 93% yield of o-hydrazotoluene.

Workup

  1. additionwas added to the reaction mixture

Sources & evidence

ORD record
ord-d524baec9fd0403192822ba1bbb041a5
Source dataset
uspto-grants-1983_03
Patent number
US04375559

Reaction notes

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