HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
5-(S)-methyl-7-(t-butyldimethylsilyloxy)-2-heptene → (3S)-3-Methylheptan-1-OL
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 5-(S)-methyl-7-(t-butyldimethylsilyloxy)-2-heptene | HCID 53780377 | — |
| Edukt | HCID 178418361 | HCID 178418361 | — |
| Katalysator | Palladium hydroxide | HCID 9942167 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | (3S)-3-Methylheptan-1-OL | HCID 12490717 | — |
Reaktionsschritte
To a solution of 74.8 g. of 5-(S)-methyl-7-(t-butyldimethylsilyloxy)-2-heptene in 500 ml. of methanol was added 7.5 g. of 10% palladium hydroxide on carbon and the mixture shaken in a hydrogen atmosphere for 1.5 hours at 50 psi. The catalyst was filtered and the solvent removed under vacuum, 30 g.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04767743 |
| Quelldatensatz | uspto-grants-1988_08 |
| ORD ID | ord-01daf8a69ff143439ee15aa2712ff87a |
| Quellennotiz | uspto-grants-1988_08 |